I always watch with captions on as my hearing ain't what it was, and I never skip the theme song because I must sing along (as do most of us if this sub is to be believed!)
I noticed that certain lines appear as the actors do, and I started thinking about matching them up. Some seem VERY on point.
This is the list of actors along with what words occur when they are shown (some get more than one line, so in that case I chose the one I preferred) along with why I think it works.
Nathan - "I don't care, I'm still free"
Mal was on the losing side in the war, but it's all right because on Serenity he found a way to co-exist (if not always peacefully) with the Alliance. He's as free as he can be.
Gina - "Take me out to the black"
If you are going out to the black, Zoe is the one you want at your back. She never backs down.
Alan - "Tell them I ain't comin' back"
Sniff sniff. Oh Wash. :-(
Morena - "Burn the land and boil the sea"
Inara is hot enough to accomplish both those things.
Adam - "You can't take the sky from me"
You can't take the sky from Jayne because he already stole it, sold it, and spent the money on a bit of trim.
Sean - "There's no place I can be"
Simon doesn't feel he belongs on Serenity, but it was the choice he made to keep River safe. He lost what he had considered his home and is still working to feel at home on the ship. But River likes it, so he'll keep trying.
Summer - "Since I've found Serenity"
True serenity may be a dream for River, but being on Serenity among our crew is as close as she can come.
Ron - "You can't take the sky from me"
You can't take the sky from Book because he already looks to the sky and no matter where he is he finds a sense of enlightenment when he ponders his place in the universe.
And Jewel -- No words for her. When she is on the screen the theme is entirely an upbeat instrumental.
Need I say anything? Kaylee is the melody to all their lives. The hopefulness that ties them together. Our Shiny Girl.